Material Safety Data Sheet
Barium manganate(vi), 95%

ACC# 88218
Section 1 - Chemical Product and Company Identification
MSDS Name: Barium manganate(vi), 95%
Catalog Numbers: AC198480000, AC198480250, AC198481000
Synonyms:
None.
Company Identification:

              Acros Organics N.V.
              One Reagent Lane
              Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300

Section 2 - Composition, Information on Ingredients

CAS# Chemical Name Percent EINECS/ELINCS
7787-35-1 Barium manganate(VI), 95% 95% 232-109-6

Section 3 - Hazards Identification

EMERGENCY OVERVIEW

Appearance: green solid.
Danger! Strong oxidizer. Contact with other material may cause a fire. Causes eye, skin, and respiratory tract irritation. Moisture sensitive. The toxicological properties of this material have not been fully investigated.
Target Organs: None.


Potential Health Effects
Eye: Causes eye irritation.
Skin: Causes skin irritation.
Ingestion: May cause gastrointestinal irritation with nausea, vomiting and diarrhea.
Inhalation: Causes respiratory tract irritation.
Chronic: No information found.

Section 4 - First Aid Measures


Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin: Get medical aid. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion: Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician: Treat symptomatically and supportively.

Section 5 - Fire Fighting Measures


General Information: Strong oxidizer. Contact with other material may cause fire.
Extinguishing Media: Use water only!
Flash Point: Not available.
Autoignition Temperature: Not available.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating: Not published.

Section 6 - Accidental Release Measures


General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Reduce airborne dust and prevent scattering by moistening with water. Clean up spills immediately, observing precautions in the Protective Equipment section.

Section 7 - Handling and Storage


Handling: Wash thoroughly after handling. Wash hands before eating. Use with adequate ventilation. Do not breathe dust, vapor, mist, or gas. Do not get on skin or in eyes. Do not ingest or inhale.
Storage: Do not store near combustible materials. Store in a cool, dry place. Store in a tightly closed container.

Section 8 - Exposure Controls, Personal Protection


Engineering Controls: Use adequate general or local explosion-proof ventilation to keep airborne levels to acceptable levels.
Exposure Limits
Chemical Name ACGIH NIOSH OSHA - Final PELs
Barium manganate(VI), 95% 0.5 mg/m3 TWA (listed under Barium). 1 mg/m3 TWA (as Mn) (listed under Manganese compounds, n.o.s.).500 mg/m3 IDLH (as Mn) (listed under Manganese compounds, n.o.s.). 0.5 mg/m3 TWA (listed under Barium).5 mg/m3 Ceiling (as Mn) (listed under Manganese compounds, n.o.s.).

OSHA Vacated PELs: Barium manganate(VI), 95%: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - Physical and Chemical Properties


Physical State: Solid
Appearance: green
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Vapor Density: 4.8500
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point:Not available.
Decomposition Temperature:Not available.
Solubility: slightly soluble
Specific Gravity/Density:4.8500g/cm3
Molecular Formula:BaMnO4
Molecular Weight:256.27

Section 10 - Stability and Reactivity


Chemical Stability: Stable under normal temperatures and pressures.
Conditions to Avoid: Incompatible materials, combustible materials, exposure to moist air or water.
Incompatibilities with Other Materials: Acids, reducing agents, and moisture.
Hazardous Decomposition Products: No data available.
Hazardous Polymerization: Has not been reported.

Section 11 - Toxicological Information


RTECS#:      
CAS# 7787-35-1 unlisted.
LD50/LC50:
Not available.

Carcinogenicity:
CAS# 7787-35-1: Not listed by ACGIH, IARC, NTP, or CA Prop 65.

Epidemiology: No information available.
Teratogenicity: No information available.
Reproductive Effects: No information available.
Mutagenicity: No information available.
Neurotoxicity: No information available.
Other Studies:

Section 12 - Ecological Information

No information available.

Section 13 - Disposal Considerations

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.

Section 14 - Transport Information

US DOT Canada TDG
Shipping Name: BARIUM COMPOUNDS, N.O.S. BARIUM COMPOUNDS NOS (BARIUM MANGANATE)
Hazard Class: 6.1 6.1
UN Number: UN1564 UN1564
Packing Group: III III

Section 15 - Regulatory Information

US FEDERAL

TSCA
     CAS# 7787-35-1 is listed on the TSCA inventory.
Health & Safety Reporting List
     None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
     None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
     None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
     None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
     None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
     None of the chemicals in this product have a TPQ.
Section 313
     This material contains Barium manganate(VI), 95% (listed as Barium), 95%, (CAS# 7787-35-1) which is subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR Part 373.
Clean Air Act:
     CAS# 7787-35-1 (listed as Manganese compounds, n.o.s.) is listed as a      hazardous air pollutant (HAP).
     This material does not contain any Class 1 Ozone depletors.
     This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
     None of the chemicals in this product are listed as Hazardous Substances under the CWA.
     None of the chemicals in this product are listed as Priority Pollutants under the CWA.
     None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
     None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
     CAS# 7787-35-1 can be found on the following state right to know lists: California, (listed as Manganese compounds, n.o.s.), New Jersey, (listed as Barium), Pennsylvania, (listed as Barium), Pennsylvania, (listed as Manganese compounds, n.o.s.), Pennsylvania, (listed as Barium compounds, n.o.s.), Minnesota, (listed as Manganese compounds, n.o.s.), Massachusetts, (listed as Barium).

California Prop 65

California No Significant Risk Level: None of the chemicals in this product are listed.

European/International Regulations

European Labeling in Accordance with EC Directives
Hazard Symbols:
     XN
Risk Phrases:

     R 20/22 Harmful by inhalation and if swallowed.

Safety Phrases:

     S 28A After contact with skin, wash immediately with plenty of water
     .

WGK (Water Danger/Protection)

     CAS# 7787-35-1: No information available.
Canada - DSL/NDSL
     CAS# 7787-35-1 is listed on Canada's DSL List.
Canada - WHMIS
     not available.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
     CAS# 7787-35-1 (listed as Manganese compounds, n.o.s.) is listed on the Canadian Ingredient Disclosure List.

Section 16 - Additional Information

MSDS Creation Date: 9/02/1997
Revision #3 Date: 10/03/2005

The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.